Acetate ion augmented fluorescence sensing of Zn(2+) by Salen-based probe, AIE character, and application for picric acid detection.

Counter anion-triggered metal ion detection has been rarely reported by fluorimetric method. To address this challenging issue, a fluorescent probe (H(2)L) has been synthesized from bromo-salicylaldehyde and hydrazine hydrate, and structurally characterized by single crystal X-ray diffraction. The probe shows very weak fluorescence itself. However, its emission intensity increases in the presence of Zn(2+) over other metal ions. Surprisingly, the emission profile of this probe in presence of Zn(2+) is augmented only when acetate anion (OAc¯) is present as counter anion, that allows for precise quantitative analysis by spectroscopic studies. The compositions and complexation among the probe, Zn(2+) ion, and OAc¯ are supported by ESI-MS, (1)H-NMR, and Job's plot. Based on these studies, it is confirmed that the binding ratio between probe: metal is 1:2 and the detection limit (LOD) for the Zn(2+) is 2.18 µM. The probe is capable of recognizing Zn(2+) ion in the wide range of pH∼6.5-9.5, and it could be efficiently recycled by EDTA. Furthermore, the combinatorial molecular logic gate and memory device have been constructed from the fluorescent behavior of H(2)L with Zn(2+), OAc¯, and EDTA input as based on NOT and AND gates. Interestingly, the aggregation-induced emission (AIEE) phenomenon is also perceived with greater than 50% water content in organic water mixtures, which are then useful for the detection of picric acid often used as explosive.