([2.2.2]Cryptand)potassium (4-methyl-benzene-thiol-ato)[5,10,15,20-tetra-kis-(4-chloro-phen-yl)porphyr-inato]manganate(II) tetra-hydro-furan disolvate.

Single crystals of the title compound, [K(C(18)H(36)N(2)O(6))][Mn(C(44)H(24)Cl(4)N(4))(C(7)H(7)S)]·2C(4)H(8)O, were obtained by the solvent evaporation method. The Mn(II) cation is coordinated by four pyrrole N atoms (N(p)) of the porphyrin ring and one S atom of the apical 4-methyl-benzene-thiol-ate ligand with the average Mn-N(p) and the apical Mn-S bond lengths being 2.160†(9) and 2.4642†(8)†à , respectively. Two tetra-hydro-furan solvent mol-ecules and a potassium cation chelated inside a [2.2.2]cryptand (4,7,13,16,21,24-hexa-oxa-1,10-di-aza-bicyclo[8.8.8]hexa-cosa-ne) are also present.