The title mol-ecule, C(21)H(26)N(2)O(3), adopts a V-shaped conformation and is chiral at the C atom with methyl group attached at the common cut of the edges of the V-conformation and crystallizes as a racemate. It also contains an intra-molecular O-Hâ¯N hydrogen bond. In the crystal, N-Hâ¯O hydrogen bonds form chains of mol-ecules extending along the c-axis direction, together with normal van der Waals contacts. The roles of the various inter-molecular inter-actions were clarified by Hirshfeld surface analysis, which reveals that the most important contributions to the crystal packing are from Hâ¯H (62.6%), Câ¯H/Hâ¯C (15.8%) and Oâ¯H/Hâ¯O (15.3%) contacts.
Crystal structure and Hirshfeld surface analysis of (±)-N'-(2-hy-droxy-3-meth-oxy-benzyl-idene)-2-(4-iso-butyl-phen-yl)propionohydrazide.
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作者:Mohamed Shaaban K, Mague Joel T, Akkurt Mehmet, Abdel-Rahman Laila H, Abdel-Hameed Mohamed, Albayati Mustafa R, Al-Taif Elham A
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2022 | 起止号: | 2022 Jul 29; 78(Pt 8):860-863 |
| doi: | 10.1107/S2056989022007605 | ||
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