In the crystal of the title compound, C(9)H(9)ClFN(3)S, the molecules are inter-connected by N-Hâ¯S and N-Hâ¯F hydrogen bonds. There are two different N-Hâ¯S hydrogen bond: the stronger one links mol-ecules into infinite chains along the b axis with graph-set motif C(4), while the weaker N-Hâ¯S hydrogen bond combines with the previous one into an R(2) (2)(8) network. Moreover, the chains are linked into layers parallel to (102) by weak N-Hâ¯F hydrogen bonds, which form an R(2) (2)(22) ring motif. In addition, there are also weak Ï-Ï inter-actions between the benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.8997â (15)â à ].
(E)-2-[1-(3-Chloro-4-fluoro-phen-yl)ethyl-idene]hydrazinecarbothio-amide.
阅读:18
作者:Zhai, Xiu-Rong
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Dec 11; 67(Pt 1):o76 |
| doi: | 10.1107/S1600536810051093 | ||
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