The structure of the polymeric title complex, {[Cd(C(6)H(6)N(2)O(6))(H(2)O)(3)]·2H(2)O}(n), consists of chains running parallel to [01] in which the oxamidato ligand, deprotonated only at the carboxyl-ate groups, acts as a bridging bis-monodentate ligand. The Cd atom and the O atom of a coordinated water mol-ecule are located on a twofold axis. The coordination geometry around the Cd atom is distorted trigonal-pyramidal. In the crystal structure, neighbouring chains are linked into a three-dimensional network by inter-chain O-Hâ¯O and N-Hâ¯O hydrogen bonds.
catena-Poly[[[triaqua-cadmium(II)]-μ-2,2'-[oxalylbis(azanediyl)]diacetato-κO,O'] dihydrate].
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作者:Zhou, Fangxia
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Dec 9; 66(Pt 1):m35 |
| doi: | 10.1107/S1600536809052015 | ||
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