In the title compound, [Cu(C(2)H(3)O(3))(C(12)H(8)N(2))(2)]NO(3), the Cu(II) atom is coordinated by two phenanthroline (phen) ligands and one carboxyl-O atom of a hy-droxy-acetate anion in a distorted square-pyramidal geometry. The hy-droxy group of the hy-droxy-acetate ligand links with the counter NO(3) (-) anion via a pair of bifurcated O-Hâ¯O hydrogen bonds. The centroid-centroid distance of 3.5676â (14)â à between benzene rings of parallel phen ligands of adjacent mol-ecules suggests the existence of Ï-Ï stacking. Weak inter-molecular C-Hâ¯O hydrogen bonding is also present in the crystal structure.
(2-Hy-droxy-acetato-κO)bis-(1,10-phenan-throline-κN,N')copper(II) nitrate.
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作者:Kong Ya-Jie, Yuan Zhuang-Dong
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 May 1; 67(Pt 5):m592 |
| doi: | 10.1107/S1600536811013110 | ||
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