The title complex, [Ni(2)(C(6)H(2)N(3)O(7))(2)(C(10)H(20)N(4)O(4))], contains a centrosymmetric binuclear unit in which the oxamide ligand (located on a centre of symmetry) acts in a bis--tetra-dentate fashion and the picrate anion binds to nickel(II) in a bidentate mode. The Ni(II) atom displays a distorted octa-hedral coordination with axial elongation. The binuclear mol-ecules are linked by inter-molecular N-Hâ¯O, O-Hâ¯O and C-Hâ¯O hydrogen bonds into a two-dimensonal supra-molecular network extending parallel to (100).
{μ-trans-N,N'-Bis[2-(2-hydroxy-ethyl-amino)eth-yl]oxamidato(2-)}bis-[picrato-nickel(II)].
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作者:Tian, Chunliang
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Dec 16; 66(Pt 1):m71 |
| doi: | 10.1107/S1600536809052933 | ||
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