In the title methanol disolvate complex, [Ni(4)(C(14)H(16)N(3)O(4))(2)(ClO(4))(2)(C(10)H(8)N(2))(2)]·2CH(3)OH, the neutral tetra-nickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is a square pyramid. The separations of the Ni atoms bridged by the oxamide and carboxyl groups are 5.227â (9) and 5.268â (6)â à , respectively. In the crystal structure, a two-dimensional supramolecular network structure involving O-Hâ¯O and C-Hâ¯O hydrogen bonding is observed.
Bis(2,2'-bipyridine)bis-{μ(3)-cis-N-(2-carboxyl-atophen-yl)-N'-[3-(dimethyl-amino)prop-yl]oxamidato(3-)}-bis(per-chlorato)-tetra-nickel(II) methanol disolvate.
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作者:Tian Chunliang, Gao Zhongjun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Nov 28; 65(Pt 12):m1691 |
| doi: | 10.1107/S160053680905017X | ||
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