The title complex, [Cu(2)(C(13)H(16)N(3)O(3))(C(12)H(8)N(2))(H(2)O)]NO(3), consists of a nitrate ion and a binuclear Cu(II) unit in which the oxamide ligand has a cis geometry, is fully deprotonated and acts in a bidentate fashion to one Cu(II) atom and in a tetradentate fashion to the other Cu(II) atom. The Cu(II) atom coordination geometries are distorted square-planar and distorted square-pyramidal. In the crystal structure, binuclear complexes and nitrate ions are connected by classical O-Hâ¯O and non-classical C-Hâ¯O hydrogen bonds into a three-dimensional framework. The alkyl chains of the anion are equally disorded over two positions.
Aqua-{μ-N-[3-(dimethyl-amino)-prop-yl]-N'-(2-oxidophen-yl)oxamidato(3-)}(1,10-phenanthroline)dicopper(II) nitrate.
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作者:Gao Zhongjun, Wang Yanbao
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Sep 11; 66(Pt 10):m1249-50 |
| doi: | 10.1107/S1600536810035919 | ||
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