The title compound, C(19)H(19)N(5)O(2), was prepared by the reaction of 3-amino-5-(pyridin-3-yl)-1,2,4-triazole with acetone and 2-hy-droxy-3-eth-oxy-benzaldehyde. It crystallizes from ethanol in a tetra-gonal space group, with one mol-ecule in the asymmetric unit. The 1,2,4-triazole five-membered ring is planar (maximum deviation = 0.0028â à ). The pyridine and phenyl rings are also planar with maximum deviations of 0.0091 and 0.0094â à , respectively. In the crystal, N-Hâ¯N hydrogen bonds link the mol-ecules into supra-molecular chains propagating along the c-axis direction. Hirshfeld surface analysis and two-dimensional fingerprint plots have been used to analyse the inter-molecular inter-actions present in the crystal.
Crystal structure and Hirshfeld surface analysis of 7-eth-oxy-5-methyl-2-(pyridin-3-yl)-11,12-di-hydro-5,11-methano-[1,2,4]triazolo[1,5-c][1,3,5]benzoxadiazo-cine.
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作者:Aydemir Ercan, Kansiz Sevgi, Gumus Mustafa Kemal, Gorobets Nikolay Yu, Dege Necmi
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2018 | 起止号: | 2018 Feb 20; 74(Pt 3):367-370 |
| doi: | 10.1107/S2056989018002621 | ||
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