The mol-ecule of the title nicotinonitrile derivative, C(22)H(19)BrN(2)O(2), is non-planar, the central pyridine ring making dihedral angles of 7.34â (14) and 43.56â (15)° with the 4-bromo-phenyl and 4-ethoxy-phenyl rings, respectively. The eth-oxy group of the 4-ethoxy-phenyl is slightly twisted from the attached benzene ring [C-O-C-C = 174.2â (3)°], whereas the eth-oxy group attached to the pyridine ring is in a (+)syn-clinal conformation [C-O-C-C = 83.0â (3)°]. A weak intra-molecular C-Hâ¯N inter-action generates an S(5) ring motif. In the crystal structure, the mol-ecules are linked by weak inter-molecular C-Hâ¯N inter-actions into screw chains along the b axis. These chains stacked along the a axis. Ï-Ï inter-actions with centroid-centroid distances of 3.8724â (16) and 3.8727â (16)â à are also observed.
6-(4-Bromo-phen-yl)-2-eth-oxy-4-(4-ethoxy-phen-yl)nicotinonitrile.
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作者:Chantrapromma Suchada, Fun Hoong-Kun, Suwunwong Thitipone, Padaki Mahesh, Isloor Arun M
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Dec 9; 66(Pt 1):o79-80 |
| doi: | 10.1107/S1600536809051861 | ||
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