Synthesis, crystal structure, spectroscopic features and Hirshfeld surfaces of 2-methyl-3-[(2-methyl-phen-yl)carbamo-yl]phenyl acetate.

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作者:Yaman Mavişe, Cakmak Şukriye, Dege Necmi, Odabaşoğlu Mustafa, Pavlenko Vadim A, Kutuk Halil
The title compound, C(17)H(17)NO(3), was synthesized, characterized by IR spectroscopy and its crystal structure was determined from single-crystal diffraction data. The asymmetric unit contains two mol-ecules, which adopt different conformations. In one mol-ecule, the acet-oxy and the terminal 2-methyl-phenyl groups are positioned on opposite sides of the plane formed by the central benzene ring, whereas in the other mol-ecule they lie on the same side of this plane. In the crystal, the mol-ecules are linked through strong N-H⋯O hydrogen bonds into chains along [010]. Hirshfeld surface analysis and fingerprint plots were used to investigate the inter-molecular inter-actions in the solid state.

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