Crystal structure of ethyl 2-[(4-bromo-phen-yl)amino]-3,4-di-methyl-pent-3-enoate.

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作者:Zukerman-Schpector Julio, Caracelli I, Stefani Hélio A, Khan Amna N, Tiekink Edward R T
In the title compound, C15H20BrNO2, there are two independent mol-ecules (A and B) comprising the asymmetric unit and these adopt very similar conformations. In A, the dihedral angle between the CO2 and MeC=CMe2 groups is 80.7†(3)°, and these make dihedral angles of 3.5†(3) and 84.09†(16)°, respectively, with the bromo-benzene ring. The equivalent dihedral angles for mol-ecule B are 78.4†(3), 2.1†(3) and 78.37†(12)°, respectively. The most prominent inter-actions in the crystal packing are amine-N-H⋯O(carbon-yl) hydrogen bonds between the two independent mol-ecules, resulting in non-centrosymmetric ten-membered {⋯OC2NH}2 synthons. Statistical disorder is noted for each of the terminal methyl groups of the ethyl residues.

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