The title pyridazinone derivative, C(21)H(19)ClN(2)O(3), is not planar. The unsubstituted phenyl ring and the pyridazine ring are inclined to each other, making a dihedral angle of 17.41â (13)° whereas the Cl-substituted phenyl ring is nearly orthogonal to the pyridazine ring [88.19â (13)°]. In the crystal, C-Hâ¯O hydrogen bonds generate dimers with R (2) (2)(10) and R (2) (2)(24) ring motifs which are linked by C-Hâ¯O inter-actions, forming chains extending parallel to the c-axis direction. The inter-molecular inter-actions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most significant contributions to the crystal packing are from Hâ¯H (44.5%), Câ¯H/Hâ¯C (18.5%), Hâ¯O/Hâ¯O (15.6%), Clâ¯H/Hâ¯Cl (10.6%) and Câ¯C (2.8%) contacts.
Crystal structure and Hirshfeld surface analysis of ethyl 2-[5-(3-chloro-benz-yl)-6-oxo-3-phenyl-1,6-di-hydro-pyridazin-1-yl]acetate.
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作者:El Kalai Fouad, Baydere Cemile, Daoui Said, Saddik Rafik, Dege Necmi, Karrouchi Khalid, Benchat Noureddine
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2019 | 起止号: | 2019 May 24; 75(Pt 6):892-895 |
| doi: | 10.1107/S2056989019007424 | ||
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