In the racemic title compound, C(23)H(20)N(2)O(4)S, the sulfur atom is attached equatorially to the sugar ring with unequal S-C bonds, viz.: S-C(s) = 1.808â (2) and S-C(p) = 1.770â (2)â à (s = sugar, p = pyrid-yl). The dihedral angles between the pyridine ring and its attached phenyl groups are 42.24â (8) and 6.37â (14)°. In the crystal, a system of classical O-Hâ¯O and O-Hâ¯(O,O) hydrogen bonds links the mol-ecules to form tube-like assemblies propagating parallel to the c-axis direction. Weak C-Hâ¯N inter-actions are also observed.
Crystal structure of racemic 2-[(β-arabino-pyran-osyl)-sulfanyl]-4,6-diphenylpyridine-3-carbo-nitrile.
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作者:Hammad Sherif F, Masoud Doaa M, Elgemeie Galal H, Jones Peter G
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2018 | 起止号: | 2018 May 25; 74(Pt 6):853-856 |
| doi: | 10.1107/S2056989018007284 | ||
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