Pressure Dependence of Structural Behavior in the Polymorphs of Fe(PM-BiA)(2)(NCS)(2).

The pressure dependence of structural behavior in the orthorhombic (Pccn, PI) and monoclinic (P2(1)/c, PII) polymorphs of the compound [Fe(PM-BiA)(2)(NCS)(2)], where PM-BiA = (N-(2'-pyridylmethylene)-4-amino-bi-pheynyl), is studied with synchrotron single-crystal X-ray diffraction and vibrational spectroscopy. Both polymorphs are stable up to ∼1.5 GPa, with a spin state transition occurring only in polymorph PII under hydrostatic conditions as documented by single-crystal synchrotron diffraction. The diffraction data also provide evidence of the formation of superstructures for both PI, with a doubled c axis, and PII, with a doubled b axis, on applying pressures above 2 GPa. The LS and HS states seem to coexist at high-pressures for both polymorphs studied with synchrotron infrared spectroscopy at quasi-hydrostatic conditions. Such results indicate that the occurrence of spin-crossover transformations in [Fe(PM-BiA)(2)(NCS)(2)] might strongly depend on the stress in the sample.