Superiority of Cellulose Non-Solvent Chemical Modification over Solvent-Involving Treatment: Solution for Green Chemistry (Part I).

In the following article, a new approach of cellulose modification, which does not incorporate any solvents (NS), is introduced. It is compared for the first time with the traditional solvent-involving (S) treatment. The analysed non-solvent modification process is carried out in a planetary mill. This provides the opportunity for cellulose mechanical degradation, decreasing its size, simultaneously with ongoing silane coupling agent grafting. Fourier-transform infrared spectroscopy (FT-IR) indicated the possibility of intense cleavage of the glucose rings in the cellulose chains during the mechano-chemical treatment. This effect was proved with dynamic light scattering (DLS) results-the size of the particles decreased. Moreover, according to differential scanning calorimetry (DSC) investigation, modified samples exhibited decreased moisture content and a drop in the adsorbed water evaporation temperature. The performed research proved the superiority of the mechano-chemical treatment over regular chemical modification. The one-pot bio-filler modification approach, as a solution fulfilling green chemistry requirements, as well as compromising the sustainable development rules, was presented. Furthermore, this research may contribute significantly to the elimination of toxic solvents from cellulose modification processes.