Seaweed-Liked WS₂/rGO Enabling Ultralong Cycling Life and Enhanced Rate Capability for Lithium-Ion Batteries

海藻状 WS₂/rGO 可实现锂离子电池的超长循环寿命和增强倍率能力

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作者:Yi Huang, Yu Jiang, Zhaofei Ma, Yan Zhang, Xianfeng Zheng, Xuemin Yan, Xiaoqing Deng, Wei Xiao, Haolin Tang

Abstract

WS&sub2; is considered as a potential anode material for lithium ion batteries (LIBs) with superior theoretical capacity and stable structure with two-dimensional which facilitates to the transportation and storage of lithium ion. Nevertheless, the commercial recognition of WS&sub2; has been impeded by the intrinsic properties of WS&sub2;, including poor electrical conductivity and large volume expansion. Herein, a seaweed-liked WS&sub2;/reduced graphene oxide (rGO) composites has been fabricated through a procedure involving the self-assembling of WO&sub4;2-, hexadecyl trimethyl ammonium ion with graphene oxide (GO) and the subsequent thermal treatment. The WS&sub2;/rGO nanocomposite exhibited the outstanding electrochemical property with a stable and remarkable capacity (507.7 mAh·g-1) at 1.0 A·g-1 even after 1000 cycles. This advanced electrochemical property is due to its seaweed-liked feature which can bring in plentiful active sites, ameliorate the stresses arisen from volume variations and increase charge transfer rate.

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