Synthesis and Characterization of Renewable Polyester Coil Coatings from Biomass-Derived Isosorbide, FDCA, 1,5-Pentanediol, Succinic Acid, and 1,3-Propanediol

以生物质衍生的异山梨醇、FDCA、1,5-戊二醇、琥珀酸和 1,3-丙二醇为原料合成并表征可再生聚酯卷材涂料

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作者:Mónica Lomelí-Rodríguez, José Raúl Corpas-Martínez, Susan Willis, Robert Mulholland, Jose Antonio Lopez-Sanchez

Abstract

Biomass-derived polyester coatings for coil applications have been successfully developed and characterized. The coatings were constituted by carbohydrate-derived monomers, namely 2,5-furan dicarboxylic acid, isosorbide, succinic acid, 1,3-propanediol, and 1,5-pentanediol, the latter having previously been used as a plasticizer rather than a structural building unit. The effect of isosorbide on the coatings is widely studied. The inclusion of these monomers diversified the mechanical properties of the coatings, and showed an improved performance against common petrochemical derived coatings. This research study provides a range of fully bio-derived polyester coil coatings with tunable properties of industrial interest, highlighting the importance of renewable polymers towards a successful bioeconomy.

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