Decoration of Vertically Aligned Carbon Nanotubes with Semiconductor Nanoparticles Using Atomic Layer Deposition

使用原子层沉积技术将半导体纳米粒子修饰成垂直排列的碳纳米管

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作者:Anna Szabó, László Péter Bakos, Dániel Karajz, Tamás Gyulavári, Zsejke-Réka Tóth, Zsolt Pap, Imre Miklós Szilágyi, Tamás Igricz, Bence Parditka, Zoltán Erdélyi, Klara Hernadi

Abstract

Vertically aligned carbon nanotubes (VACNTs or "CNT forest") were decorated with semiconductor particles (TiO&sub2; and ZnO) by atomic layer deposition (ALD). Both the structure and morphology of the components were systematically studied using scanning (SEM) and high resolution transmission electron microscopy (HRTEM), energy-dispersive X-ray spectroscopy (EDX), Raman spectroscopy, and X-ray diffraction (XRD) methods. Characterization results revealed that the decoration was successful in the whole bulk of VACNTs. The effect of a follow-up heat treatment was also investigated and its effect on the structure was proved. It was attested that atomic layer deposition is a suitable technique for the fabrication of semiconductor/vertically aligned carbon nanotubes composites. Regarding their technological importance, we hope that semiconductor/CNT forest nanocomposites find potential application in the near future.

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