Design, synthesis, and anti-Toxoplasma gondii evaluation of β-carboline derivatives

β-咔啉衍生物的设计、合成及其抗弓形虫活性评价

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Abstract

BACKGROUND: The current therapeutic options for toxoplasmosis are limited by side effects. The development of molecules against T. gondii is urgently needed. A series of β-carboline derivatives were synthesized and examined as potential agents against toxoplasmosis. METHODS: A series of β-carboline derivatives were synthesized. To assess their potential as anti-T. gondii agents, cytotoxicity towards Vero cells was determined using the CCK-8 assay. Plaque and qPCR assays were carried out to screen for anti-T. gondii activities, providing insights into their inhibitory effects on the parasite. In vitro assays on T. gondii RH and PRU strains were conducted to evaluate proliferation, invasion, and cyst formation. Transmission electron microscopy was employed to analyze ultrastructural changes and apoptosis in T. gondii, revealing the impact of the derivatives at the cellular level. Finally, the in vivo efficacy of the derivatives was tested in a mouse model, which offered valuable information on their potential therapeutic effects in a living organism. RESULTS: β-carboline derivatives exhibited potent inhibitory effects on the growth and replication of both PRU and RH strains, while demonstrating low cytotoxicity to mammalian cells. It is worth noting that NBZ023 and NBZ035 exhibited optimal potency against proliferation (IC(50) = 2.85 and 1.6 μM) or invasion (IC(50) = 4.72 and 1.13 μM) of T. gondii. Importantly, NBZ023 and NBZ035 had an effect on preventing PRU cysts formation, and they markedly reduced parasite burden in the brain, spleen, and liver in mouse infection model. CONCLUSIONS: Lead compounds NBZ023 and NBZ035 exhibited an excellent overall efficacy against the T. gondii RH and PRU strains, and were highly effective at preventing toxoplasmosis during murine infection, which are expected to be developed as new anti-toxoplasmosis drugs.

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