Carbon Microparticles from Organosolv Lignin as Filler for Conducting Poly(Lactic Acid)

有机溶剂木质素碳微粒作为导电聚乳酸的填料

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作者:Janea Köhnke, Christian Fürst, Christoph Unterweger, Harald Rennhofer, Helga C Lichtenegger, Jozef Keckes, Gerhard Emsenhuber, Arunjunai Raj Mahendran, Falk Liebner, Wolfgang Gindl-Altmutter

Abstract

Carbon microparticles were produced from organosolv lignin at 2000 °C under argon atmosphere following oxidative thermostabilisation at 250 °C. Scanning electron microscopy, X-ray diffraction, small-angle X-ray scattering, and electro-conductivity measurements revealed that the obtained particles were electrically conductive and were composed of large graphitic domains. Poly(lactic acid) filled with various amounts of lignin-derived microparticles showed higher tensile stiffness increasing with particle load, whereas strength and extensibility decreased. Electric conductivity was measured at filler loads equal to and greater than 25% w/w.

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