Functional Printing of Conductive Silver-Nanowire Photopolymer Composites

导电银纳米线光聚合物复合材料的功能印刷

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作者:Tomke E Glier, Lewis Akinsinde, Malwin Paufler, Ferdinand Otto, Maryam Hashemi, Lukas Grote, Lukas Daams, Gerd Neuber, Benjamin Grimm-Lebsanft, Florian Biebl, Dieter Rukser, Milena Lippmann, Wiebke Ohm, Matthias Schwartzkopf, Calvin J Brett, Toru Matsuyama, Stephan V Roth, Michael Rübhausen

Abstract

We investigated the fabrication and functional behaviour of conductive silver-nanowire-polymer composites for prospective use in printing applications. Silver-nanowires with an aspect ratio of up to 1000 were synthesized using the polyol route and embedded in a UV-curable and printable polymer matrix. Sheet resistances in the composites down to 13 Ω/sq at an optical transmission of about 90% were accomplished. The silver-nanowire composite morphology and network structure was investigated by electron microscopy, atomic force microscopy, profilometry, ellipsometry as well as surface sensitive X-ray scattering. By implementing different printing applications, we demonstrate that our silver nanowires can be used in different polymer composites. On the one hand, we used a tough composite for a 2D-printed film as top contact on a solar cell. On the other hand, a flexible composite was applied for a 3D-printed flexible capacitor.

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