Chemical Modification of Cellulose Microfibres to Reinforce Poly(methyl methacrylate) Used for Dental Application

纤维素微纤维化学改性以增强牙科用聚甲基丙烯酸甲酯

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作者:Joanna Taczała, Jacek Sawicki, Joanna Pietrasik

Abstract

The mechanical properties of dental acrylic resins have to be improved in the case of a thin denture plate. This can be achieved by cellulose addition, playing the role of active filler. But to provide the excellent dispersion of cellulose microfibres within the hydrophobic polymer matrix, its surface has to be modified. Cellulose microfibres with average length from 8 to 30 μm were modified with octyltriethoxysilane and (3-methacryloxypropyl)methyldimethoxysilane. The latter also participated in the polymerisation reaction of methyl methacrylate. Dental composites were prepared following the general procedure provided by the supplier. The successful modification of the microfibres led to the improved compatibility of the cellulose and poly(methyl methacrylate). The fibres after modification were uniformly distributed within the matrix, resulting in the improved mechanical performance of obtained materials. Cellulose microfibres are good candidates for the dental materials to be used as the active filler. The simple and straightforward approach for the cellulose modifications with silanes provides good potential for its future practical application.

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