Fabrication and Characterization of Sulfonated Graphene Oxide (SGO) Doped PVDF Nanocomposite Membranes with Improved Anti-Biofouling Performance

磺化氧化石墨烯 (SGO) 掺杂 PVDF 纳米复合膜的制备及表征,提高抗生物污染性能

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作者:Muhammad Zahid, Tayyaba Khalid, Zulfiqar Ahmad Rehan, Talha Javed, Saba Akram, Anum Rashid, Syed Khalid Mustafa, Rubab Shabbir, Freddy Mora-Poblete, Muhammad Shoaib Asad, Rida Liaquat, Mohamed M Hassan, Mohammed A Amin, Hafiz Abdul Shakoor

Abstract

Emergence of membrane technology for effective performance is qualified due to its low energy consumption, no use of chemicals, high removal capacity and easy accessibility of membrane material. The hydrophobic nature of polymeric membranes limits their applications due to biofouling (assemblage of microorganisms on surface of membrane). Polymeric nanocomposite membranes emerge to alleviate this issue. The current research work was concerned with the fabrication of sulfonated graphene oxide doped polyvinylidene fluoride (PVDF) membrane and investigation of its anti-biofouling and anti-bacterial behavior. The membrane was fabricated through phase inversion method, and its structure and morphology were characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-rays diffraction (XRD) and thermo gravimetric analysis (TGA) techniques. Performance of the membrane was evaluated via pure water flux; anti-biofouling behavior was determined through Bovine Serum albumin (BSA) rejection. Our results revealed that the highest water flux was shown by M7 membrane about 308.7 Lm-2h-1/bar having (0.5%) concentration of SGO with improved BSA rejection. Furthermore, these fabricated membranes showed high antibacterial activity, more hydrophilicity and mechanical strength as compared to pristine PVDF membranes. It was concluded that SGO addition within PVDF polymer matrix enhanced the properties and performance of membranes. Therefore, SGO was found to be a promising material for the fabrication of nanocomposite membranes.

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