Intranasally delivered fucoidan nanozyme-decorated photosynthetic Chlamydomonas regulates vascular pathology and hypoxia in diabetes-associated retinal microvascular dysfunction

鼻内递送的岩藻聚糖纳米酶修饰的光合衣藻可调节糖尿病相关视网膜微血管功能障碍中的血管病理和缺氧。

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Abstract

Diabetic retinopathy (DR) is a leading cause of vision loss and is strongly associated with microvascular pathology and retinal hypoxia. Here, we report an intranasally delivered microalgae drug delivery system, Chlamydomonas@Pro-Fu-PEDOT nanozymes (CHL@Pro-Fu-PEDOT-NZs), engineered to target retinal injury. Under 660-nm red-light irradiation, the platform exploits the photosynthetic activity of Chlamydomonas to generate bioelectric cues and therapeutic gases (O(2)), thereby alleviating hypoxia and reducing vascularization. Fucoidan functionalization further confers P-selectin-mediated vascular addressing, enabling lesion-focused delivery and regulation of hypoxia-driven vascular responses through photosynthesis-inspired gas generation and bioelectrical modulation. In vitro, CHL@Pro-Fu-PEDOT-NZs exhibited excellent biocompatibility and protected retinal ganglion cells from oxidative and inflammatory injury. In a streptozotocin (STZ)-induced DR mouse model, intranasal delivery mitigated pathological retinal responses, as evidenced by reduced VEGF and HIF-1α expression, and yielded measurable improvements in visual behavior, without detectable systemic toxicity. Collectively, this multifunctional, noninvasive therapeutic platform offers strong potential for DR treatment by simultaneously addressing vascular dysfunction, and hypoxia.

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