Effect of sulphidation process on the structure, morphology and optical properties of GO/AgNWs composites

硫化过程对GO/AgNWs复合材料的结构、形貌和光学性质的影响

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Abstract

In this study, composite materials composed of graphene oxide (GO) synthesized by a modified Hummers' method and silver nanowires (AgNWs) synthesized by a modified polyol method were prepared. The prepared composites were subjected to sulfidation under the influence of H(2)S gas. Structural changes in the samples were evaluated using X-ray diffraction (XRD). The binding nature of the composite was characterized using FT-IR spectroscopy. Optical properties and band gap values were investigated using ultraviolet-visible (UV-Vis) spectroscopy. The morphology of the composites was analyzed by transmission electron microscopy (TEM). A simple method using H(2)S gas was applied for the sulphidation process of the samples. The sulfidation process was successful under the influence of H(2)S gas, resulting in an increased distance between the GO layers and a decrease in the band gap value for the composite post-sulfidation. In addition, AgNWs were observed to decompose into Ag(2)S nanoparticles under the influence of H(2)S gas. It was determined that the value of the band gap of the sample changes because of sulphidation.

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