Nanoscale Perovskite-Sensitized Solar Cell Revisited: Dye-Cell or Perovskite-Cell?

纳米级钙钛矿敏化太阳能电池再探:染料敏化电池还是钙钛矿敏化电池?

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Abstract

A general and straightforward way of preparing few-nanometer-sized well-separated MAPbI(x) Br(3-x) (MA=methylammonium) perovskite photosensitizers on the surface of an approximately 1 μm thick mesoporous TiO(2) photoanode was suggested through a two-step sequential deposition of low-concentrated lead halides (0.10-0.30 m PbI(2) or PbBr(2) ) and methylammonium iodide/bromide (MAI/MABr). When those nanoscale MAPbI(x) Br(3-x) perovskites were incorporated as a photosensitizer in typical solid-state dye-sensitized solar cells (ss-DSSCs), it could be verified clearly by the capacitance analysis that nano-particulate MAPbI(3) perovskites play the same role as that of a typical dye sensitizer (MK-2 molecule) although their size, composition, and structure are different.

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