Moving Electrode Impedance Spectroscopy for Accurate Conductivity Measurements of Corrosive Ionic Media

移动电极阻抗谱法用于腐蚀性离子介质电导率的精确测量

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Abstract

A measurement cell for the use of accurate conductivity measurements of corrosive ionic media is presented. Based on the concept of moving electrode electrochemical impedance spectroscopy, exceptional measurement accuracy is achieved in a large conductivity range. Extensive testing with corrosive ionic media demonstrated the robust operation of the cell under harsh chemical conditions, up to temperatures of 130 °C. The novel design allows monitoring small conductivity changes during chemical reactions in ionic media, for instance, zeolite formation from hydrated ionic liquids.

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