Analysis of the structural continuity in twinned crystals in terms of pseudo-eigensymmetry of crystallographic orbits

基于晶体学轨道伪本征对称性的孪晶结构连续性分析

阅读:1

Abstract

The reticular theory of twinning gives the necessary conditions on the lattice level for the formation of twins. The latter are based on the continuation, more or less approximate, of a substructure through the composition surface. The analysis of this structural continuity can be performed in terms of the eigensymmetry of the crystallographic orbits corresponding to occupied Wyckoff positions in the structure. If [Formula: see text] is the space group of the individual and [Formula: see text] a space group which fixes the twin lattice obtained as an intersection of the space groups of the individuals in their respective orientations, then a structural continuity is obtained if (1) the eigensymmetry of an orbit under [Formula: see text] contains the twin operation; (2) the eigensymmetry of a union of orbits under [Formula: see text] contains the twin operation; (3) the eigensymmetry of a split orbit under [Formula: see text] contains the twin operation; or (4) the eigensymmetry of a union of split orbits under [Formula: see text] contains the twin operation. The case of the twins in melilite is analysed: the (approximate) restoration of some of the orbits explains the formation of these twins.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。