Abstract
Molecule intercalation has shown distinct advantages in modulating the superconducting properties of 2D materials. Chiral molecule intercalation provides a strategy for tuning electronic properties, while this approach has been limited to a few 2D materials such as TaS(2) and TiS(2). Although extensive research on 2D SnSe(2) exists, chiral molecule intercalation in SnSe(2) remains unexplored. Herein, we report the first successful electrochemical intercalation of chiral CTA cations (CTA = 3-chloro-2-hydroxypropyltrimethylammonium) into SnSe(2) by using piezoelectric R/S-CTA-Cl with a large piezoelectric coefficient of approximately 24 pm/V as the precursors, leading to the formation of superconductors R/S-CTA-SnSe(2). Characterization techniques, including powder X-ray diffraction, Raman spectroscopy, and circular dichroism spectroscopy, confirm a significant lattice expansion in SnSe(2) and the successful intercalation of chiral CTA cations, while polar R/S-CTA-Cl does not endow R/S-CTA-SnSe(2) with piezoelectric/ferroelectric properties. Magnetic susceptibility and electrical transport measurements reveal that the intercalated R/S-CTA-SnSe(2) materials exhibit a superconducting transition at around 5 K. Notably, the distinct out-of-plane and in-plane upper critical magnetic fields demonstrate the 2D nature of the intercalated compounds. This work highlights an approach for designing and tailoring superconducting materials through chiral cation intercalation and opens avenues for further exploration of chiral effects in superconductors.