Abstract
Zn-based aqueous batteries (ZABs) hold great promise for large-scale energy storage applications due to the merits of intrinsic safety and low cost. Nevertheless, the thorny issues of metallic Zn anodes, including dendrite growth and parasitic side reactions, have severely limited the application of ZABs. Despite the encouraging improvements for stabilizing Zn anodes through surface modification, electrolyte optimization, and structural design, fundamentally addressing the inherent thermodynamics and kinetics obstacles of Zn anodes remains crucial in realizing reliable ZABs with ultrahigh efficiency, capacity, and cyclability. The target of this perspective is to elucidate the prominent status of Zn metal anode electrochemistry first from the perspective of zincophilicity and zincophobicity. Recent progress in ZABs is critically appraised for addressing the key issues, with special emphasis on the trade-off between zincophilic and zincophobic electrochemistry. Challenges and prospects for further exploration of a reliable Zn anode are presented, which are expected to boost in-depth research and practical applications of advanced ZABs.