Abstract
The high-throughput screening investigations on TiO(2) based photocatalyst composites presented here have been carried out in a 60-fold parallel photoreactor. Additional catalyst testing was performed in a microslit reactor system with immobilized catalysts. For further enhancing the photocatalytic activity of TiO(2) (P25), composites of P25 and, for example, Bi(2) O(3) , CeO(2) , g-C(3) N(4) , WO(3) or ZnO were formulated in different nominal molar ratios. The catalysts' performances were assessed by their conversion of 17α-ethinyl estradiol (EE2) in aqueous solutions, determined by LC-MS. Findings show rapid EE2 conversions in short residence times. The extensive testing of catalysts led to the conclusion that the photocatalytic conversion is rather a function of residence time than a function of the materials utilized. This makes adequate process development seem more important than material development. The novelty of this contribution lies in the unique combination of testing a wide range of composite catalysts in a unique microreactor geometry.