Abstract
Propane-1,3-diaminium squarate dihydrate, C(3)H(12)N(2) (2+)·C(4)O(4) (2-)·2H(2)O, results from the proton-transfer reaction of propane-1,3-di-amine with squaric acid and subsequent crystallization from aqueous medium. The title compound crystallizes in the tetra-gonal crystal system (space group P4bm) with Z = 2. The squarate dianion belongs to the point group D (4h) and contains a crystallographic fourfold axis. The propane-1,3-diaminium dication exhibits a C (2v) -symmetric all-anti conformation and resides on a special position with mm2 site symmetry. The orientation of the propane-1,3-diaminium ions makes the crystal structure polar in the c-axis direction. The solid-state supra-molecular structure features a triperiodic network of strong hydrogen bonds of the N-H⋯O and O-H⋯O types.