Abstract
Discharging untreated dye-containing wastewater gives rise to environmental pollution. The present study investigated the removal efficiency and adsorption mechanism of Acid Red 18 (AR18) utilizing hexadecyl-trimethyl ammonium chloride (HDTMA.Cl) modified Nano-pumice (HMNP), which is a novel adsorbent for AR18 removal. The HDTMA.Cl is characterized by XRD, XRF, FESEM, TEM, BET and FTIR analysis. pH, contact time, initial concentration of dye and adsorbent dose were the four different parameters for investigating their effects on the adsorption process. Response surface methodology-central composite design was used to model and improve the study to reduce expenses and the number of experiments. According to the findings, at the ideal conditions (pH = 4.5, sorbent dosage = 2.375 g/l, AR18 concentration = 25 mg/l, and contact time = 70 min), the maximum removal effectiveness was 99%. The Langmuir (R(2) = 0.996) and pseudo-second-order (R(2) = 0.999) models were obeyed by the adsorption isotherm and kinetic, respectively. The nature of HMNP was discovered to be spontaneous, and thermodynamic investigations revealed that the AR18 adsorption process is endothermic. By tracking the adsorption capacity of the adsorbent for five cycles under ideal conditions, the reusability of HMNP was examined, which showed a reduction in HMNP's adsorption effectiveness from 99 to 85% after five consecutive recycles.