Abstract
New paramagnetic Ni(I)(IMes)(2)X (IMes: 1,3-bis-(2,4,6-trimethylphenyl)-imidazol-2-ylidene) were prepared from the reaction of Ni(IMes)(2) with aryl halides. Products that would arise from oxidative addition were not observed. In contrast, Ni(II)(tmiy)(2)(X)(Ar) was formed from the oxidative addition of aryl halides to Ni bound by a sterically-less hindered NHC ligand, tmiy (tetramethylimidazol-2-ylidene). The paramagnetic Ni(I)(IMes)(2)X complexes were compared to known Ni(0) and Ni(II) catalysts for Kumada and Suzuki coupling reactions. Stoichiometric reactions between the Ni(I)(IMes)(2)X complexes with aryl halides and transmetallating agents were also evaluated.