Abstract
A homologous family of low-coordinate complexes of the formulation trans-[M(2,2'-biphenyl)(PR(3) )(2) ][BAr(F)(4) ] (M=Rh, Ir; R=Ph, Cy, iPr, iBu) has been prepared and extensively structurally characterised. Enabled through a comprehensive set of solution phase (VT (1) H and (31) P NMR spectroscopy) and solid-state (single crystal X-ray diffraction) data, and analysis in silico (DFT-based NBO and QTAIM analysis), the structural features of the constituent agostic interactions have been systematically interrogated. The combined data substantiates the adoption of stronger agostic interactions for the Ir(III) compared to Rh(III) complexes and, with respect to the phosphine ligands, in the order PiBu(3) >PCy(3) >PiPr(3) >PPh(3) . In addition to these structure-property relationships, the effect of crystal packing on the agostic interactions was investigated in the tricyclohexylphosphine complexes. Compression of the associated cations, through inclusion of a more bulky solvent molecule (1,2-difluorobenzene vs. CH(2) Cl(2) ) in the lattice or collection of data at very low temperature (25 vs. 150 K), lead to small but statistically significant shortening of the M-H-C distances.