Abstract
Multireference systems are usually challenging to investigate using ab initio methods as they require an accurate description of static electron correlation. The urgency of developing similar approaches is even more pressing when molecules strongly interact with light in quantum-electrodynamics (QED) environments. In fact, in this context, multireference effects might be induced or reduced by the presence of the field. In this work, we extend the complete active space self-consistent field (CASSCF) approach to polaritonic systems. The method is tested on benchmark multireference problems and applied to investigate field-induced effects on the electronic structure of well-known multiconfigurational processes. Strengths and limitations of the method have been thoroughly analyzed.