Trimethyl 2,2',2''-[1,3,5-triazine-2,4,6-tri-yltris-(aza-nedi-yl)]triacetate

2,2',2''-[1,3,5-三嗪-2,4,6-三基三-(氮杂二基)]三乙酸三甲酯

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作者:Sérgio M F Vilela, Filipe A Almeida Paz, João P C Tomé, Verónica de Zea Bermudez, José A S Cavaleiro, João Rocha

Abstract

The title compound, C(12)H(18)N(6)O(6), was synthesized via nucleophilic substitution by reacting 2,4,6-trichloro-1,3,5-triazine with glycine methyl ester hydro-chloride in reflux (dried toluene) under anhydrous atmosphere. Individual mol-ecules self-assemble via strong N-H⋯O hydrogen bonds into supra-molecular double tapes running parallel to the [010] crystallographic direction. The close packing of supra-molecular tapes is mediated by geometrical reasons in tandem with a number of weaker N-H⋯O and C-H⋯N hydrogen-bonding inter-actions.

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