Tricarbonyl-bis-(1,3-diisopropyl-4,5-dimethyl-imidazol-2-yl-idene)iron

三羰基双(1,3-二异丙基-4,5-二甲基咪唑-2-亚基)铁

阅读:1

Abstract

In the title compound, [Fe(C11H20N2)2(CO)3], the Fe atom shows a distorted trigonal-bipyramidal geometry with three carbonyl and two carbene ligands. The latter have a cis arrangement, with a C-Fe-C angle of 90.60 (7)°. The Fe atom lies 0.007 (1) Å above the basal plane defined by two carbonyl and one carbene C atoms. The mol-ecular structure is closely related to that of the isomolecular but not isotypic Ru complex with an identical cis arrangement, so, in general, bond geometries lie in expected ranges. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into infinite zigzag chains extending along [010].

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。