Abstract
The silicate Earth contains Pt-group elements in roughly chondritic relative ratios, but with absolute concentrations <1% chondrite. This veneer implies addition of chondrite-like material with 0.3-0.7% mass of the Earth's mantle or an equivalent planet-wide thickness of 5-20 km. The veneer thickness, 200-300 m, within the lunar crust and mantle is much less. One hypothesis is that the terrestrial veneer arrived after the moon-forming impact within a few large asteroids that happened to miss the smaller Moon. Alternatively, most of terrestrial veneer came from the core of the moon-forming impactor, Theia. The Moon then likely contains iron from Theia's core. Mass balances lend plausibility. The lunar core mass is ~1.6 × 10(21) kg and the excess FeO component in the lunar mantle is 1.3-3.5 × 10(21) kg as Fe, totaling 3-5 × 10(21) kg or a few percent of Theia's core. This mass is comparable to the excess Fe of 2.3-10 × 10(21) kg in the Earth's mantle inferred from the veneer component. Chemically in this hypothesis, Fe metal from Theia's core entered the Moon-forming disk. H(2)O and Fe(2)O(3) in the disk oxidized part of the Fe, leaving the lunar mantle near a Fe-FeO buffer. The remaining iron metal condensed, gathered Pt-group elements eventually into the lunar core. The silicate Moon is strongly depleted in Pt-group elements. In contrast, the Earth's mantle contained excess oxidants, H(2)O and Fe(2)O(3), which quantitatively oxidized the admixed Fe from Theia's core, retaining Pt-group elements. In this hypothesis, asteroid impacts were relatively benign with ~1 terrestrial event that left only thermophile survivors.