Abstract
Cellulosic substrates such as dairy cow manure often yield low volumes of biogas and low concentrations of methane when digested anaerobically. Thermal pretreatment of dairy cow manure was investigated to determine if pretreatment temperature and duration can be optimized to maximize biogas yield and methane concentration. A central composite rotatable design was used to select combinations of temperature and duration. Based on measured data, statistical models were generated to estimate the biogas yield and methane concentration during digestion. The highest biogas yields were from the untreated samples and samples treated at the center temperature and duration of the statistical model (125 °C, 37.5 min). The model predicted the optimum pretreatment conditions of 140 °C for 30 minutes. Under the conditions of this experiment, temperature and duration had no significant effect on the biogas yield and methane concentration. This lack of significance may indicate that thermal pretreatment may be an unnecessary step in the anaerobic digestion of dairy cow manure, which could reduce capital and operating costs for the industry.