Food seasoning-derived gel polymer electrolyte and pulse-plasma exfoliated graphene nanosheet electrodes for symmetrical solid-state supercapacitors

食品调味料衍生的凝胶聚合物电解质和脉冲等离子体剥离石墨烯纳米片电极用于对称固态超级电容器

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Abstract

Kitchen sea salt or table salt is used every day by cooks as a food seasoning. Here, it is introduced into a gel polymer (poly(vinyl) alcohol (PVA)-table salt) for use as an electrolyte, and an electrode was constructed from graphene nanosheets for use as symmetrical solid-state supercapacitors. The graphene sheets are prepared by a pulse control plasma method and used as an electrode material, and were studied by X-ray diffraction (XRD), Raman spectroscopy, as well as scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). A specific capacitance of 117.6 F g(-1) at 5 mV s(-1) was obtained in a three electrode system with table sea salt as an aqueous electrolyte. For a symmetrical solid-state supercapacitor: graphene/PVA-table sea salt/graphene gave a good specific capacitance of 31.67 F g(-1) at 0.25 A g(-1) with an energy density of 6.33 W h kg(-1) at a power density of 600 W kg(-1), with good charge-discharge stability, which was 87% after 8000 cycles. Thus, the development of table sea salt as an environmentally friendly electrolyte has a good potential for use in energy storage applications.

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