Abstract
Utilizing ultrasonic vibrations, the nano-supramolecular complex [(phen)(3)Cu(2)(CN)(3) (H(2)O)(5)] (NSC1) was obtained. NSC1 was inlaid with nano-titanium oxide to create composite (TiO(2)/NSC1) nanoparticles using ultrasonic waves. ICP, XRPD, SEM, TEM, TGA, and other spectroscopic methods were applied to characterize the composite. Both NSC1 and TiO(2)/NSC1 function as heterogeneous catalysts against methylene blue (MB) and brilliant green (BG) dyes, which were assessed and compared. When H(2)O(2) is present, it has an effective capacity to degrade (MB) and (BG) dyes. However, the nanocomposite exhibits exceptional degradation efficiency using UV or ultrasonic waves under a variety of conditions. To clarify the mechanisms of mineralization, scavenger techniques, the terephthalic acid disodium salt photoluminescence technique and spectrophotometric titration were used. The TiO(2)/NSC1 nanocomposite's photoluminescence property was analyzed and estimated. So, the composite can ability to operate as a highly efficient selective luminous sensor, which showed outstanding detection and highly effective quenching of the nanocomposite's photofluorescence towards nitrobenzene, Na(+), and Mn(2+) ions.