Novel Hybrid Conductor of Irregularly Patterned Graphene Mesh and Silver Nanowire Networks

一种新型的由不规则图案石墨烯网和银纳米线网络构成的混合导体

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Abstract

We prepared the hybrid conductor of the Ag nanowire (NW) network and irregularly patterned graphene (GP) mesh with enhanced optical transmittance (~98.5%) and mechano-electric stability (ΔR/R(o): ~42.4% at 200,000 (200k) cycles) under 6.7% strain. Irregularly patterned GP meshes were prepared with a bottom-side etching method using chemical etchant (HNO(3)). The GP mesh pattern was judiciously and easily tuned by the regulation of treatment time (0-180 min) and concentration (0-20 M) of chemical etchants. As-formed hybrid conductor of Ag NW and GP mesh exhibit enhanced/controllable electrical-optical properties and mechano-electric stabilities; hybrid conductor exhibits enhanced optical transmittance (TT = 98.5%) and improved conductivity (ΔR(s): 22%) compared with that of a conventional hybrid conductor at similar TT. It is also noteworthy that our hybrid conductor shows far superior mechano-electric stability (ΔR/R(o): ~42.4% at 200k cycles; TT: ~98.5%) to that of controls (Ag NW (ΔR/R(o): ~293% at 200k cycles), Ag NW-pristine GP hybrid (ΔR/R(o): ~121% at 200k cycles)) ascribed to our unique hybrid structure.

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