Nanoporous Carbon Derived from Green Material by an Ordered Activation Method and Its High Capacitance for Energy Storage

通过有序活化法从绿色材料制备纳米多孔碳及其高储能性能

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Abstract

Carbon materials have been widely used as electrode materials for supercapacitors, while the current carbon precursors are mainly derived from fossil fuels. Biomass-derived carbon materials have become new and effective materials for electrodes of supercapacitors due to their sustainability, low pollution potential, and abundant reserves. Herein, we present a new biomass carbon material derived from water hyacinth by a novel activation method (combination of KOH and HNO(3) activation). According to the electrochemical measurements, the material presents an ultrahigh capacitance of 374 F g(-1) (the current density is 1 A g(-1)). Furthermore, the material demonstrates excellent rate performance (105 F g(-1) at a higher density of 20 A g(-1)) and ideal cycling stability (87.3% capacity retention after 5000 times charge-discharge at 2 A g(-1)). When used for a symmetrical supercapacitor device, the material also shows a relatively high capacity of 330 F g(-1) at 1 A g(-1) (a two-electrode system). All measurements suggest the material is an effective and noteworthy material for the electrodes of supercapacitors.

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