A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst

一种利用固定在聚砜纤维网络纳米粒子上的新型生物活性钴复合材料作为催化剂的醇氧化绿色化学方法

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作者:Andrés Alexis Ramírez-Coronel, Salim Oudah Mezan, Indrajit Patra, Ramaswamy Sivaraman, Yassine Riadi, Shukhrat Khakberdiev, Holya A Lafta, Munther Abosaooda, Abduladheem Turki Jalil, Yasser Fakri Mustafa

Abstract

In this study, cobalt composite immobilized on polysulfone fibrous network nanoparticles (CCPSF NPs) were synthesized in a controllable and one-step way under microwave-assisted conditions. The structure of CCPSF NPs was characterized by SEM images (for morphology and size distribution), TGA (for thermal stability), BET technique (for the specific surface area), FT-IR spectroscopy (for relation group characterization), and XRD patterns (for crystal size). The oxidation of the primary and secondary alcohols to aldehyde and ketone was investigated using synthesized CCPSF NPs under solvent-free microwave-assisted conditions, and high oxidizing activity was observed. In addition to oxidation properties, the anticancer activity of the synthesized CCPSF NPs in breast cancer was evaluated by the MTT method , and significant results were obtained.

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