Template-Sacrificing Synthesis of Ni-Co Layered Double Hydroxides Polyhedron as Advanced Anode for Lithium Ions Battery

利用模板牺牲法合成镍钴层状双氢氧化物多面体作为锂离子电池先进负极材料

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Abstract

The novel hollowed Ni-Co layered double hydroxide polyhedron (H-(Ni, Co)-LDHP) is synthesized via a template-sacrificing approach using ZIF-67 as template. The morphology, crystallinity, porous texture, and chemical state of H-(Ni, Co)-LDHP are examined. It demonstrates that the H-(Ni, Co)-LDHP not only provides rich redox sites but also promotes the kinetics due to presence of numerous rational channels. As a result, the H-(Ni, Co)-LDHP manifests the desirable lithium ions storage performance when employed as anode. This study paves a new way for preparing hollowed nanostructure toward advanced electrochemical applications.

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