catena-Poly[[bis-[[bis-(3-amino-prop-yl)amine-κN,N',N''](thio-cyanato-κN)cadmium]-μ(4)-sulfato-κO,O:O',O'] methanol hemisolvate]

链状聚[[双-[[双-(3-氨基-丙基)胺-κN,N',N''](氰硫基-κN)镉]-μ(4)-硫酸基-κO,O:O',O']甲醇半溶剂化物]

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Abstract

The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio-cyanate and one sulfate anion, two bis-(3-amino-prop-yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thio-cyanate anion and one bis-(3-amino-prop-yl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octa-hedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further μ-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis.

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