Abstract
This study examined the emission and physicochemical properties of microplastics and nanoplastics (MPs/NPs) generated during shredding, which is regularly used in mechanical recycling. Waste and new polyethylene terephthalate, polypropylene, and high-density polyethylene were investigated herein for a total of six categories. The concentration and size distribution of particles were measured using two spectrometer instruments, and morphology and elemental composition of emitted particles were analyzed with microscopy and spectroscopy. This study found that number concentrations in both submicron and micron sizes of respirable particles were 3-2910× higher during periods of shredding than pre-shredding background concentrations. Maximum concentrations of particles within 10-420 nm, across all six categories, ranged from 22,000- to 1,300,000-particles/cm(3) during shredding, compared to average background levels of 700 particles/cm(3). Maximum concentrations of particles within 0.3 to 10 μm, across all six categories, ranged from 24- to 2000-particles/cm(3) during shredding, compared to average background levels of 2 particles/cm(3). Waste plastics consistently generated higher emissions than their new counterparts, which is attributed to the labels, adhesives, and increased additives incorporated into the waste plastic. Morphology varied drastically between particles and an elemental composition analysis found that the samples consisted primarily of C and O, representing the polymer material, as well as Na, Mg, Al, Si, Cu, Cl, K, Ca, Ti, Fe, Rb, and Br representing additives, label, and other contaminates. The shredding of plastic has the potential to expose workers to elevated concentrations of airborne MPs/NPs, especially those between 10 and 100 nm.